Defrost shrimp in water according to instructions on the package.
At the same time, bring water to a boil. Once water is boiling, add rice.
Once rice has absorbed the water (if it hasn't absorbed all the water but is soft in texture, drain excess water), transfer to a skillet with olive oil.
Cook rice over medium-high heat for 5 minutes, then add achiote and kale; mix well.
While the rice is cooking, cook shrimp in a separate skillet with chili powder, paprika and a drop of olive oil.
Once rice and shrimp are cooked, combine into one bowl.
Enjoy!